Tag: bioplastic

After a failed print, I decided to rationalise my moulds. These are created via a parametric tentacle design program in OpenSCAD. Obviously, changing the mould requires program changes, but this time my goals were both to ensure that it can create a mould across a wide range of parameters for users who want unusual sizes and to include an optimal ratio of parameters based on actuator research.

My program does not cope with tiny sizes. It’s expected that tentacles designed with it will be nearly as long as the print bed of a Ultimaker or longer. However, it seems likely that optimal ratios will be constant across actuator sizes. I adopted the ratios given by K Ogura et al, developed for tiny actuators. (2009)

As their actuators are squared and mine still have rounded edges, it may be that these are not optimal, however, I do feel that the new, narrow mould has higher aesthetic appeal.

Silicon

Before trying to cast this, I went to the 4d Model Shop to discuss the difficulties I had with my last silicon cast. The person working around the casting section of the store is extremely knowledgeable and helpful. She suggested that what I needed was a lower viscosity silicone, but as I still have a quite a lot of the high viscosity left, she suggested I paint the mould with a small amount of it, close the mould, mix up a second small batch and pour that in the top. She suggested that may allow the silicon to flow through the entire mould before it sets. Unfortunately, the shop does not sell retarder.

She also told me that although silicon does not adhere to PLA, the porousness of a 3d printed PLA mould creates a lot of surface irregularity that silicon will flow into, making the two part mould extremely difficult to separate. The mould must first be sealed.

Epoxy sealant is toxic and may contain elements that prevent silicon from curing, so she suggested I experiment with a high gloss polyurethane sealant and then paint liquid Vaseline over that as a release agent.

I painted a single coat of sealant on one mould section, followed by the vaseline. I then mixed up a tiny batch of silicon. During this process, the scale turned itself off, so I was forced to estimate ratios of the two part compound. I therefore used two mould sections, one as a control group in case the haphazard ratio has curing problems.

The experimental section had a thicker piece of silicon and was made slippery by the Vaseline, which may be why it was more difficult to remove that the section that had no treatments.

My next steps will be to:

• try a different sealant
• try using more coats of the existing sealant
• try using non-liquid vaseline to better cover over cracks in the mould
• try using other household materials such as sunflower oil or sudo cream

Bioplastic

I’ve currently got a small batch of corn plastic drying, which is taking more than a week. The volume is decreasing significantly and I’m not sure it will be enough to make a test cast once it dried enough for me to melt it.

I’ve found some very promising research about using food waste to make bioplastic. The experiment was done using a dilute solution of hydrochloric acid – so dilute that vinegar is more acidic. I wish to see if vinegar would also produce this result, but it requires a food dehydrator and the ability to stir a solution at 40C for more than day – so a magnetic stirrer hotplate.

There is also research about citrus peels, specifically. This is perhaps the most interesting avenue. Pectins are stretchy like gelatin, which has been tested in actuators. It’s also easily available in my area. The processing is very much like other food waste processing, so the same equipment is required.

Feelings

This is all taking much much much longer than I thought it would and I have to say, I’m starting to feel extremely discouraged. While the 3d programming has turned out to be a lot easier for me than I anticipated, virtually everything else has been vastly more difficult. I was hoping to have some kind of prototype by autumn, but this looks less and less likely. My workshop access has been through my primary employer, the University of Kent. However, the department I teach in is closing and thus I’m becoming redundant over the summer. It’s still unclear whether the arts workshop is also closing at this time.

Cooking bioplastics in the kitchen is extremely unpopular with my spouse and I don’t really have space for a food dehydrator. I hope the London Hackspace may be able to help with this, however, they’ve moved rather a long way from the old neighbourhood.

Works cited

Bátori, V et al (2017). Production of Pectin-Cellulose Biofilms: A New Approach for Citrus Waste Recycling. International Journal of Polymer Science [Online] , vol. 2017, Article ID 9732329, 9 pages, 2017. Available at: https://www.hindawi.com/journals/ijps/2017/9732329/cta/ DOI: 10.1155/2017/9732329 [Accessed May 2019]

Keiko Ogura et al (2009). Micro pneumatic curling actuator – Nematode actuator. 2008 IEEE International Conference on Robotics and Biomimetics. [Online] Available at: https://ieeexplore.ieee.org/abstract/document/4913047 DOI: 10.1109/ROBIO.2009.4913047 [Accessed May 2019]

Perotto, G et al (2018). Bioplastics from vegetable waste via an eco-friendly water-based process. Green Chemistry, [online] 20, pp. 894-902. Available at: https://pubs.rsc.org/en/content/articlelanding/2018/gc/c7gc03368k/unauth#!divAbstract DOI: 10.1039/C7GC03368K [Accessed May 2019]

Mould Revisions following a Pour Attempt

As reported in my previous post, I created some moulds out of PLA for silicon casting. The second version of the mould fit together well. It had a single pour hole in the larger outside block.

When pouring silicon into this hole, there was no route for air to escape the mould and the silicon was slow moving within the mould. The silicon began to harden before even a fraction of the pour was complete.

Despite the small amount of silicon that got into the mould, it was extremely difficult to open, showing that the use of a release agent is necessary. Also, the slowness of the pour shows that a retarder is required.

I’ve made two versions of an updated mould. The larger mould piece has additional channels for which silicon to flow in and small air channels for air to flow out. There are now two identical pour holes and two smaller air holes. The airholes are connected to a narrow channel running for the length of the mould, which connects to the topmost part of the internal cavities. This should allow air to escape and if some silicon gets into the channels, it should not cause a problem.

The other half of the mould has two new designs. The aesthetically superior one cuts out a round channel for silicon flow. This channel is the same diameter as the cut-outs of the other part of the mould, which should give it a unified look. However, this creates an overhang. As the tentacle will be cast in a soft material, it should hopefully be possible to peel the tentacle from the mould without doing it damage.

Because the overhang may fail, I’ve also created a version of that half of the mould that has narrower protrusions. This should also allow better pouring channels for silicon, but will cause the walls of the finished tentacle to be much thicker on the outside edge.

Bioplastic

In the mean time, I’ve been experimenting with bioplastic and food waste. PLA is sort of biodegradable and recyclable, but silicon is not.

Banana Peel Plastic

My first attempt at bioplastic was overly ambitious. Banana peels contain starch, so I used those. I used a lime peel as an acidic element to get free ions. I added coffee grounds as well. For preservative, I added a mixture of sage and tea tree essential oils. And used glycerol as the plasticiser.

Ingredients

• 1 lime (post juicing for another recipie)
• 3 banana peels
• 1 moka pot’s worth of spent coffee grounds
• 0.5 tsp tea tree oil
• 1 tsp sage oil
• 0.5 tsp vinegar
• 2 tsp glycerol

Procedure

• boil the limes and insufficient amount amount of time. save the water.
• boil the banana peels 30 minutes
• dry the banana peels 30 minues
• blend the fruit and coffee with enough lime water to make a paste.
• cook until thickens
• Apply to final shape
• Bake at a low oven temperature to dry

Results

The shape I attempted to make was a flower pot, moulded over an empty jar. While the material did mostly bond together, it took more than a week to fully dry and has had some cracking.

Some of this may be due to how ripe the peels were- presumably this caused some of the starches to convert to sugars. Also, I failed to remove any parts of any peels, so fibres and stems got into the final product. While these were unintentional, they have probably aided the stability of the structure.

Corn Flour Plastic

My second attempt used corn flour (also known as corn starch), vinegar, salt, glycerol and coffee grounds.

For this, I used slightly more corn flour than I’d use for gravy, as much liquid as I would use for custard, a teaspoon of glycerol, a teaspoon of vinegar and a few pinches of rock salt.

I cooked all of the ingredients together until they started to thicken like custard. I then transferred the mixture to a takeway container and added a teaspoons of sage essential oil as a preservative. I applied the mixture to paper maché animal horns, and put it in the oven at a low heat.

These took a day to dry, but the plastic has come out successfully. While I don’t have any good measurements for ingredient ratios, it seems I used a large amount of glycerol relative to the corn starch. This created a very flexible rubbery plastic, not altogether unlike silicon in consistency.

Bioplastic Actuators

Previous research into bioplastic soft robotics is available. The paper, Soft Pneumatic Gelatin Actuator for Edible Robotics [DOI: 10.1109/IROS.2017.8206525], especially caught my fancy. While a theatrical robot falls outside of their potential applications (which charmingly suggests “food transportation where the robot does not require additional payload because the robot is the food.” (Shintake, et al., 2017, p 6221)), an edible robot is a biodegradable robot.

Using food for non food applications also has ethical issues, however. Part of my goal with bioplastics is to utilise food waste and as such, I will be investigating the possibility of highly flexible banana peel actuators. Although the starch in these peels is edible, it’s usually discarded. Using this for plastic thus reduces food waste and potentially may help highlight the culturally-based waste of edible items.

Finally, I can make this kind of plastic in my kitchen and don’t need to access a workshop.

First Tentacle Attempt

My first bioplastic tentacle section used an unmeasured corn flour plastic similar to the plastic above. It contained no vinegar but instead copious amounts of sea salt, as this also frees up ions and may help preserve the plastic. For additional acidity, I scavenged a lime that had not been juiced to the fullest possible extent and squeezed the remainder into the plastic. The preservative was 1 tsp tea tree oil. As I did not strain the lime, some pulp got in, probably rendering moot the various preservative attempts.

I brushed the inside of the mould with sunflower oil. Corn flour bioplastic starts to set even more quickly than silicon and there are really only a few seconds to decant it into the mould. As such, I did not use the pours holes, but instead spooned the plastic into the mould and struck the lid with my hand to force it down. Excess plastic leaked from the top and pour holes.

The drying process for starch bioplastic seems to rely on access to air, so it was still completely uncured after several days and was damaged by opening the mould to check on it.

Shintake et al, mentioned above, used gelatin-based bioplastic, which may be better suited to this application. This is also often a food-waste product, however, it’s made via an industrial process using waste from the meat industry (Etxabide, et al., 2017) and is not something I could really make at home. I’ll be looking at whether I can extract pectin from fruit peels and use it for plastic.

Unresolved Issues

As all the tentacles need to be identical, proper measurements and consistency will become extremely important.

My moulds are designed to create the tentacle in two parts which must be joined together with an airtight seal. While this seems straightforward in silicon, I don’t yet know how difficult it will be with bioplastic. Perhaps a hybrid silicon/bioplastic tentacle is the answer, as I do not actually want my robot to be eaten.

The durability of this material is also unknown. One design studio on YouTube says that essential oils act as preservatives, but it’s unclear how long this prevents decay.

References

Bilgin, E. (2013). Banana peel plastic – Science DIY. [online] Sites.google.com. Available at: https://sites.google.com/site/scidiy/diy-plastic/banana-peel-plastic [Accessed 7 May 2019].

Borroni, L. (2018). DIY bioplastics from orange peels and ground coffee – YouTube. [online] Youtube.com. Available at: https://www.youtube.com/embed/PrUjjzznwEE [Accessed 7 May 2019].

Etxabide, A., Uranga, J., Guerrero, P. and de la Caba, K. (2017). Development of active gelatin films by means of valorisation of food processing waste: A review. Food Hydrocolloids, [online] 68, pp.192-198. Available at: https://www.sciencedirect.com/science/article/pii/S0268005X16303605 [Accessed 7 May 2019].

Shintake, J., Sonar, H., Piskarev, E., Paik, J. and Floreano, D. (2017). Soft pneumatic gelatin actuator for edible robotics. 2017 IEEE/RSJ International Conference on Intelligent Robots and Systems (IROS).

wikiHow Staff Editor (2019). How to Make Bioplastic. [online] wikiHow. Available at: https://www.wikihow.com/Make-Bioplastic [Accessed 7 May 2019].